Here are the general requirements for effectively matching LiFePO4 batteries: When configuring a battery pack, it's crucial to select cells with similar performance characteristics, including voltage, capacity, and internal resistance. Using cells with comparable features improves the balance and consistency of the pack.
Battery packs with well-matched cells perform better than those in which the cell or group of cells differ in serial connection. Quality Li-ion cells have uniform capacity and low self-discharge when new. Adding cell balancing is beneficial especially as the pack ages and the performance of each cell decreases at its own pace.
Six battery packs (each containing two cells connected in parallel, as depicted in Fig. 5) were tested using the method described below. For further reference within this paper, two parallel-connected cells are called a “cell group”. The current to each cell and the temperature of each cell were recorded.
We demonstrate the importance of resistance matching in battery packs. At 4.5C charge and discharge, 20% resistance mismatch reduces lifetime by 40%. We quantitatively explain experimental results using a model of SEI formation. Resistance mismatch causes uneven current sharing.
For example, a common nominal voltage is 3.2V, with capacities often around 100Ah. Cells within the battery pack should have similar capacities to ensure the total pack capacity meets expected energy storage and release needs. Charge/discharge testing is commonly used for evaluating and matching cell capacities.
Assuming the battery pack will be balanced the first time it is charged and in use. Also, assuming the cells are assembled in series. If the cells are very different in State of Charge (SoC) when assembled the Battery Management System (BMS) will have to gross balance the cells on the first charge.
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